Debye shielding

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Within the plasma the electric potential \Phi(\mathbf{r})\, may fluctuate, in response to, and producing, fluctuations in the charge density \rho_i\, of each species. The potential energy of a single particle of each species is given by q_i \Phi(\mathbf{r})\, (which is independent of its momentum), so that the density of each species is given by Maxwell-Boltzmann statistics

n_i(\mathbf{r}) = n_{i,0} e^{-q_i \Phi(\mathbf{r})/k_B T_i}\,,

and the charge density is

\rho(\mathbf{r}) = \sum_i q_i n_{i,0} e^{-q_i \Phi(\mathbf{r})/k_B T_i}\,.

If the plasma is very hot, i.e., k_B T_i \gg |q_i \Phi(\mathbf{r})|\,, we can write

n_i(\mathbf{r}) \approx n_{i,0} \left( 1 -\frac{q_i \Phi(\mathbf{r})}{k_B T_i} \right)\,.

Poisson's equation reads

\nabla^2 \Phi(\mathbf{r}) = \frac{\rho(\mathbf{r})}{\epsilon_0}\,,

or

\nabla^2 \Phi(\mathbf{r}) \approx \sum_i q_i n_{i,0} -\sum_i \frac{q_i^2 n_{i,0} }{\epsilon_0 k_B T_i} \Phi(\mathbf{r})\,.

Defining the Debye length \lambda_D\, via

\frac{1}{\lambda_D^2} = \sum_i \frac{q_i^2 n_{i,0} }{\epsilon_0 k_B T_i}\,,

we obtain the Helmholtz equation

\nabla^2 \Phi(\mathbf{r}) + \frac{1}{\lambda^2} \Phi(\mathbf{r}) = \sum_i q_i n_{i,0}\,.

As we shall see, the free species have the effect of shielding or screening the usual Coulomb potential, an effect known as Debye shielding or Debye screening. For a quasineutral plasma consisting of two species with charge +e\, and -e\, respectively, at the same temperature T\,, and both with equilibrium number density n_0\,,

\nabla^2 \Phi(\mathbf{r}) + \frac{1}{\lambda^2} \Phi(\mathbf{r}) = 0\,,

where

\frac{1}{\lambda_D^2} = 2\frac{e^2 n_{0} }{\epsilon_0 k_B T}\,,

or

\lambda = \sqrt{ \frac{\epsilon_0 k_B T}{2 e^2 n_{0} } }\,.

Debye-Hückel radius

Without taking into account the complication of boundaries, the Green's function for the Laplacian in 3 dimensions is

G(\mathbf{r}) = -\frac{1}{4\pi r}\,,

while that of the Helmholtz equation is

G(\mathbf{r}) = -\frac{e^{-r/\lambda_D}}{4\pi r}\,.

This is easily verified by recalling that

\nabla^2 \Phi = \frac{1}{r}\frac{\partial^2}{\partial r^2} (r \Phi) + ...,

and so we see that a point charge q\, sets up a screened Coulomb potential

\Phi(\mathbf{r}) = \frac{q e^{-r/\lambda_D}}{4\pi\epsilon_0 r}\,,

which decays rapidly outside of a sphere of radius r_D = \lambda_D\,, known as the Debye-Hückel radius.

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